Synthesis and applications of a new class of C2 symmetric phosphorus donor ligand for asymmetric catalysis.

被引:26
|
作者
Brenchley, G
Fedouloff, M
Merifield, E
Wills, M
机构
[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND
[2] SMITHKLINE BEECHAM PHARMACEUT,HARLOW CM19 5AW,ESSEX,ENGLAND
关键词
D O I
10.1016/0957-4166(96)00368-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel class of C2-symmetric ligand has been prepared using an intramolecular cyclisation reaction of a diazaphosphole borane complex, Preliminary results of its application to the asymmetric catalysis of hydrogenation, hydrosilylation and allylic substitution reactions are described. Copyright (C) 1996 Elsevier Science Ltd
引用
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页码:2809 / 2812
页数:4
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