Preparation, Characterization, X-Ray Structure Determination and Solution Properties of some Novel Copper(I) Bisulfate and Sulfate Salts and Their Stable Derivatives

被引：7
|
作者：
Gill, Dip S. [1 ,2 ]
Singh, Raghubir [1 ,2 ]
Rana, Dilbag S. [3 ]
Wagler, Joerg [4 ]
Kroke, Edwin [4 ]
机构：
[1] Panjab Univ, Dept Chem, Chandigarh 160014, India
[2] Panjab Univ, Ctr Adv Studies Chem, Chandigarh 160014, India
[3] Himachal Pradesh Univ, Dept Chem, Shimla 171005, India
[4] Tech Univ Bergakad Freiberg, Inst Anorgan Chem, D-09596 Freiberg, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 10期
关键词：
Acetonitrile; Copper(I) Salts; Copper(I) Bisulfate; Copper(I) Sulfate; UV/Vis Spectra; Molar Conductance; (63)Cu NMR; BINARY-MIXTURES; BIS(2,9-DIMETHYL-1,10-PHENANTHROLINE)COPPER(I) PERCHLORATE; MIXED-SOLVENTS; TRANSPORT-PROPERTIES; ORGANIC-SOLVENTS; SILVER(I) SALTS; ACETONITRILE; COMPLEXES; 25-DEGREES-C; CONDUCTANCE;
D O I：
10.5560/ZNB.2011.66b1042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two highly unstable copper(I) salts, i. e. copper(I) bisulfate tetraacetonitrile, [Cu(CH(3)CN)(4)]HSO(4), and dicopper(I) sulfate octaacetonitrile, [Cu(CH(3)CN)(4)](2)SO(4), and their stable derivatives with 2,9-dimethy1-1,10-phenanthroline (DMPhen) have been prepared in pure form and characterized by elemental, spectral and chemical analysis. Single-crystal X-ray studies of [Cu(CH(3)CN)(4)]HSO(4) and its derivative [Cu(DMPhen)(2)]HSO(4) have been carried out. The solution behavior of both of these salts and their derivatives have been investigated using UVNis, IR, (63)Cu NMR spectroscopy and molar conductance in a number of non-aqueous solvents. Furthermore, a simple method for the preparation of Cu(2)SO(4) is presented.
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页码：1042 / 1048
页数：7
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