Enantioselective Hydrosilylation of N-Aryl Diaryl Ketimines

被引：3

作者：

Hu, Xiaoyan ^{[1
,2
]}

Hu, Fangzhi ^{[1
,2
]}

Zhang, Minmin ^{[1
,2
]}

Liao, Yijun ^{[1
,2
]}

Xu, Xiaoying ^{[1
,2
]}

Yuan, Weicheng ^{[1
]}

Zhang, Xiaomei ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 08期

基金：

中国国家自然科学基金;

关键词：

diarylmethylamines; diaryl ketimines; chiral Lewis base; hydrosilylation; CATALYZED ASYMMETRIC ARYLATION; CHIRAL DIENE LIGANDS; TRANSFER HYDROGENATION; ARYLBORONIC ACIDS; ARYLLITHIUM REAGENTS; PETASIS REACTION; HANTZSCH ESTERS; IMINES; DIARYLMETHYLAMINES; ADDITIONS;

D O I：

10.6023/cjoc201512049

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lewis base catalyzed enantioselective hydrosilylation of non-ortho-substituted N-aryl diaryl ketimines was realized. In the presence of 20 mol% of the optimal catalyst, the reactions provided a series of (diarylmethyl)amines with high yields (up to 97%) in moderate to good enantioselectivities (up to 89% ee). The absolute configuration of one product was determined by X-ray crystallographic analysis.

引用

页码：1895 / 1906

页数：12

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