Non-aggregated Zn(II)octa(2,6-diphenylphenoxy) phthalocyanine as a hole transporting material for efficient perovskite solar cells

被引:83
|
作者
Ramos, F. Javier [1 ,3 ]
Ince, M. [1 ,4 ]
Urbani, M. [2 ,5 ]
Abate, Antonio [1 ]
Graetzel, M. [1 ]
Ahmad, Shahzada [3 ]
Torres, T. [2 ,5 ]
Nazeeruddin, Mohammad Khaja [1 ,6 ]
机构
[1] Ecole Polytech Fed Lausanne, Swiss Fed Inst Technol, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
[2] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
[3] Abengoa Res, Seville 41014, Spain
[4] Mersin Univ, Dept Energy Syst Engn, Fac Tarsus Technol, TR-33480 Mersin, Turkey
[5] Inst Madrileno Estudios Avanzados IMDEA Nanocienc, Madrid 28049, Spain
[6] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 21413, Saudi Arabia
关键词
LOW-COST; SENSITIZERS; PERFORMANCE; PORPHYRINS; CONVERSION; LIGHT; DYES;
D O I
10.1039/c5dt00396b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A non-aggregated Zn(II)octa(2,6-diphenylphenoxy) phthalocyanine (coded as TT80) has been used as a hole-transporting material for perovskite solar cells. The cells were fabricated under three different configurations by changing the uptake solvent (chlorobenzene or toluene) and incorporating additives (bis(trifluoromethane) sulfonimide lithium salt (LiTFSI) and 4-tert-butylpyridine (TBP). A power conversion efficiency of 6.7% (AM1.5G standard conditions) was achieved for the best cell under optimized configuration.
引用
收藏
页码:10847 / 10851
页数:5
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