Solvent-free Synthesis of Propargylic Alcohols using ZnO as a New and Reusable Catalyst by Direct Addition of Alkynes to Aldehydes

被引：3

作者：

Hosseini-Sarvari, Mona ^{[1
]}

Mardaneh, Zahra ^{[1
]}

机构：

[1] Shiraz Univ, Fac Sci, Dept Chem, Shiraz 71454, Iran

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2011年 / 32卷 / 12期

关键词：

Propargylic alcohols; ZnO; Terminal alkynes; Solvent-free conditions; Aldehydes; ENANTIOSELECTIVE PHENYLACETYLENE ADDITION; IN-SITU GENERATION; GAMMA-HYDROXY-ALPHA; BETA-ACETYLENIC ESTERS; NUCLEOPHILIC-ADDITION; TERMINAL ACETYLENES; CARBONYL-COMPOUNDS; FACILE SYNTHESIS; MILD CONDITIONS; ALKYNYLATION; KETONES;

D O I：

10.5012/bkcs.2011.32.12.4297

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under solvent-free conditions, the synthesis of propargylic alcohols by direct addition of terminal alkynes to aldehydes promoted by ZnO as a novel, commercially, and cheap catalyst is described. Furthermore, the catalyst can be reused for several times without any significant loss of its catalytic activity.

引用

页码：4297 / 4303

页数：7

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