Thermal stabilization of chemical reactors. I The mathematical description of the Ender reactor

被引:9
|
作者
Gray, BF
Ball, R
机构
[1] Univ Sydney, Sch Math & Stat, Sydney, NSW 2006, Australia
[2] Macquarie Univ, Sch Chem, N Ryde, NSW 2109, Australia
关键词
Endex; thermal runaway; thermal stabilisation; thermokinetic systems; reactive thermal coupling; adiabatic reactor;
D O I
10.1098/rspa.1999.0307
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Here we describe the Ender reactor, a novel scheme for thermal control of potentially runaway reactions. The reactor is a composite of individual reactors, each of which houses either an exothermal or an endothermal reaction mixture. In this paper, which is Part I, we introduce the concept of an endothermally stabilized chemical reactor as an enthalpy-coupled thermokinetic system, and give it precise mathematical expression in the form of a four-dimensional dynamical system, for the special case of a continuous stirred tank reactor. The principle of enthalpy conservation is applied in the adiabatic case, which together with the consequence of taking the limit of a system parameter, collapses the structure of the state space to two dimensions. Criteria are defined for which the system is free of all kinds of thermal misbehaviour. This important dynamical result defines bounds for a large region of the parameter space within which this reactor may be operated safely.
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页码:163 / 182
页数:20
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