Preparation of synthetic wood composites using ionic liquids

被引:42
|
作者
Simmons, Trevor J. [1 ,2 ,3 ]
Lee, Sang Hyun [1 ,4 ,5 ]
Miao, Jianjun [3 ,5 ,6 ]
Miyauchi, Minoru [3 ]
Park, Tae-Joon [5 ]
Bale, Shyam S.
Pangule, Ravi [5 ]
Bult, Justin [3 ,7 ]
Martin, Jeffrey G. [1 ,5 ]
Dordick, Jonathan S. [1 ,3 ,6 ,8 ]
Linhardt, Robert J. [1 ,3 ,5 ,6 ,8 ]
机构
[1] Rensselaer Polytech Inst, Dept Chem & Chem Biol, Troy, NY 12180 USA
[2] Univ Autonoma San Luis Potosi, San Luis Potosi, Mexico
[3] Rensselaer Polytech Inst, Rensselaer Nanoctr, Troy, NY 12180 USA
[4] Univ Konkuk, Dept Microbial Engn, Seoul 143701, South Korea
[5] Rensselaer Polytech Inst, Dept Chem & Biol Engn, Troy, NY 12180 USA
[6] Rensselaer Polytech Inst, Ctr Biotechnol & Interdisciplinary Studies, Troy, NY 12180 USA
[7] Rensselaer Polytech Inst, Dept Mat Sci & Engn, Troy, NY 12180 USA
[8] Rensselaer Polytech Inst, Dept Biol, Troy, NY 12180 USA
关键词
CELLULOSE; DISSOLUTION; FILMS; HYDROLYSIS; LIGNINS;
D O I
10.1007/s00226-010-0395-6
中图分类号
S7 [林业];
学科分类号
0829 ; 0907 ;
摘要
Synthetic wood composite films containing cellulose, hemicelluloses, and lignin, the three major components of natural wood, were prepared in a room temperature ionic liquid solvent, 1-ethyl-3-methylimidazolium acetate, [EMIM][Ac]. Various synthetic wood composites were obtained by dissolution of individual wood components together with additives, including polyethylene glycol (PEG), chitosan, and multi-wall carbon nanotubes (MWNTs) in [EMIM][Ac]. The addition of water affords a gel that was dried in either a low humidity environment or under vacuum. Synthetic wood films showed smoother surface textures, higher water resistance, and higher tensile strengths than cellulose films formed by the same methods. Tailor-made synthetic wood composites were also prepared having a variety of desirable properties, including antimicrobial activities, controlled hydro-phobicity/philicity, high relative dielectric constant, and a high degree of cohesiveness.
引用
收藏
页码:719 / 733
页数:15
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