Investigation of p-dopant diffusion in polymer films and bulk heterojunctions: Stable spatially-confined doping for all-solution processed solar cells

被引：42

作者：

Dai, An ^{[1
]}

Wan, Alan ^{[2
]}

Magee, Charles ^{[2
]}

Zhang, Yadong ^{[3
,4
]}

Barlow, Stephen ^{[3
,4
]}

Marder, Seth R. ^{[3
,4
]}

Kahn, Antoine ^{[1
]}

机构：

[1] Princeton Univ, Dept Elect Engn, Princeton, NJ 08544 USA

[2] EAG, East Windsor, NJ 08520 USA

[3] Georgia Inst Technol, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA

[4] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

来源：

ORGANIC ELECTRONICS | 2015年 / 23卷

基金：

美国国家科学基金会;

关键词：

Lamination; Polymer; Doping; Molybdenum complex; Diffusion; ORGANIC ELECTRONIC MATERIALS; TRANSITION-METAL OXIDES; LIGHT-EMITTING-DIODES; TRANSPORT; EXCITONS; PHTHALOCYANINE; SEMICONDUCTORS; INJECTION;

D O I：

10.1016/j.orgel.2015.04.023

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The spatial stability of the soluble p-dopant molybdenum tris[1-(methoxycarbonyl)-2-(trifluoromethyl)-ethane-1,2-dithiolene] in polymer and polymer blend films is investigated via secondary ion mass spectrometry and current-voltage measurements. Bi-layer and tri-layer model structures, P3HT/doped P3HT and P3HT: ICBA/doped P3HT/P3HT: ICBA respectively, are fabricated using soft-contact transfer lamination to study the diffusion of the dopant. While the dopant is very mobile in pure P3HT, it is far more stable at the interface with the P3HT: ICBA bulk heterojunction. Our findings suggest a promising route to achieve spatially-confined doping with long-term stability, leading to hole-collection/injection contacts for all-solution processed polymer devices. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：151 / 157

页数：7

共 2 条

[1] Solution-Processed p-Dopant as Interlayer in Polymer Solar Cells
Guillain, F.
Endres, J.
Bourgeois, L.
Kahn, A.
Vignau, L.
Wantz, G.
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (14) : 9262 - 9267
[2] Reappraising the Need for Bulk Heterojunctions in Polymer-Fullerene Photovoltaics: The Role of Carrier Transport in All-Solution-Processed P3HT/PCBM Bilayer Solar Cells
Ayzner, Alexander L.
Tassone, Christopher J.
Tolbert, Sarah H.
Schwartz, Benjamin J.
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (46): : 20050 - 20060

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