Synthesis and reactivity of fluoro complexes. Part 1. Cyclooctadiene rhodium(I) complexes

被引：36
|
作者：
Vicente, J
Gil-Rubio, J
Bautista, D
机构：
[1] Univ Murcia, Fac Quim, Dept Quim Inorgan, Grp Quim Organomet, Murcia 30071, Spain
[2] Univ Murcia, SACE, Murcia 30071, Spain
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 12期
关键词：
D O I：
10.1021/ic015526e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of [RhF(COD)](n) and its triphenylphosphine adduct 2, and a preliminary study of the reactivity of 2 are reported. The reactivity of the Rh-F bond is illustrated by the reactions that lead to compounds 5 and 6. Compound 5 is the first trifluoromethyl Rh(I) complex characterized by monocrystal X-ray diffraction. Both compounds 2 and 6 are initiators of the polymerization of phenylacetylene. [GRAPHICS]
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收藏
页码：2636 / 2637
页数：2
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