Ligand exchange with thiols:: Effects on composition and morphology of colloidal CoPt nanoparticles

被引：5
|
作者：
Gehl, Bernhard [1 ]
Aleksandrovic, Vesna [2 ]
Erbacher, Martin
Juergens, Birte [1 ]
Schuerenberg, Martin [3 ]
Kornowski, Andreas [2 ]
Weller, Horst [2 ]
Baeumer, Marcus [1 ]
机构：
[1] Univ Bremen, Inst Angew & Phys Chem, D-28359 Bremen, Germany
[2] Univ Hamburg, Inst Phys Chem, D-20146 Hamburg, Germany
[3] Bruker Daltonik GmbH, D-28399 Bremen, Germany
来源：
CHEMPHYSCHEM | 2008年 / 9卷 / 06期
关键词：
bimetallic nanoparticles; ligand exchange; ligands; nanomaterials; thiols;
D O I：
10.1002/cphc.200700816
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Surfactant exchange: Compared to monometallic particles, ligand exchange on bimetallic systems is more challenging as complications can arise due to different binding affinities between the ligand molecules and the two metals. In colloidal bimetallic Co-Pt nanopartides (see figure, MHL: 6-mercaptohexan-1-ol) the treatment with thiols mainly leads to a loss of Co. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：821 / 825
页数：5
相关论文
共 50 条
  • [1] Fast and Slow Ligand Exchange at the Surface of Colloidal Gold Nanoparticles
    Dinkel, Rebecca
    Braunschweig, Bjoern
    Peukert, Wolfgang
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (03): : 1673 - 1682
  • [2] In situ spectroscopy of the ligand exchange at the surface of colloidal Au nanoparticles
    Dinkel, Rebecca
    Braunschweig, Bjoern
    Peukert, Wolfgang
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [3] Temperature effect on the ordering and morphology of CoPt nanoparticles
    Penuelas, J.
    Andreazza-Vignolle, C.
    Andreazza, P.
    Ouerghi, A.
    Bouet, N.
    SURFACE SCIENCE, 2008, 602 (02) : 545 - 551
  • [4] Evolution of the Ligand Shell Morphology during Ligand Exchange Reactions on Gold Nanoparticles
    Luo, Zhi
    Hou, Jing
    Menin, Laure
    Ong, Quy Khac
    Stellacci, Francesco
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (43) : 13521 - 13525
  • [5] Solvent Effects in Ligand Stripping Behavior of Colloidal Nanoparticles
    Mahmood, Akhlak U.
    Rizvi, Mehedi H.
    Tracy, Joseph B.
    Yingling, Yaroslava G.
    ACS NANO, 2023, 17 (14) : 13319 - 13332
  • [6] Controlling structure and morphology of CoPt nanoparticles through dynamical or static coalescence effects
    Penuelas, J.
    Andreazza, P.
    Andreazza-Vignolle, C.
    Tolentino, H. C. N.
    De Santis, M.
    Mottet, C.
    PHYSICAL REVIEW LETTERS, 2008, 100 (11)
  • [7] Reversible ligand exchange of triphenylphosphine with thiols on gold nanoparticles for Janus modification and catalyst recycling
    Li, Degui
    Liu, Tong
    Luo, Yujia
    Zhuge, Xiangqun
    Luo, Kun
    Luo, Zhihong
    Liu, Xiaoteng
    Zhang, Kui
    SEPARATION AND PURIFICATION TECHNOLOGY, 2023, 322
  • [8] In situ spectroscopy of ligand exchange reactions at the surface of colloidal gold and silver nanoparticles
    Dinkel, Rebecca
    Peukert, Wolfgang
    Braunschweig, Bjorn
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2017, 29 (13)
  • [9] Thermodynamics of Composition Dependent Ligand Exchange on the Surfaces of Colloidal Indium Phosphide Quantum Dots
    Calvin, Jason J.
    O'Brien, Erin A.
    Sedlak, Adam B.
    Balan, Arunima D.
    Alivisatos, A. Paul
    ACS NANO, 2021, 15 (01) : 1407 - 1420
  • [10] Probing the ligand exchange kinetics of phenynyl-based ligands on colloidal Au nanoparticles
    Xiang, Ting
    Zong, Jianpeng
    Xu, Wenjia
    Feng, Yuhua
    Chen, Hongyu
    MATERIALS CHEMISTRY FRONTIERS, 2021, 5 (01) : 465 - 471
12345