Application of a supported iron oxyhydroxide catalyst in oxidation of benzoic acid by hydrogen peroxide

被引：145
|
作者：
Chou, SS [1 ]
Huang, CP [1 ]
机构：
[1] Natl Chiao Tung Univ, Inst Environm Engn, Hsinchu, Taiwan
来源：
CHEMOSPHERE | 1999年 / 38卷 / 12期
关键词：
catalysis; iron oxide; oxidation; hydrogen peroxide;
D O I：
10.1016/S0045-6535(98)00474-3
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Oxidation of benzoic acid was studied via Fenton-Like reaction using an innovative supported gamma-FeOOH catalyst. The decomposition kinetics of hydrogen peroxide was investigated first. Oxidation of benzoic acid by hydrogen peroxide was performed to understand the effects of initial pH and hydrogen peroxide dosage. The treatment efficiency of benzoic acid at an initial pH of 3.2 was higher than at initial pHs of 6.0 and 10.0; this can be partly explained by reductive dissolution of gamma-FeOOH. Therefore, the extent of heterogeneous catalysis was evaluated. We found that the majority of oxidation occurred on the catalyst surface, with some occurred in the solution due to iron dissolution of the catalyst. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2719 / 2731
页数：13
相关论文
共 50 条
  • [1] Oxidation of methane to methanol by hydrogen peroxide on a supported hematin catalyst
    Nagiev, TM
    Abbasova, MT
    ZHURNAL FIZICHESKOI KHIMII, 1997, 71 (07): : 1220 - 1224
  • [2] Oxidation of Methane to Methanol by Hydrogen Peroxide on a Supported Hematin Catalyst
    Russ J Phys Chem, 7 (1088):
  • [3] Polyvinylpyridine supported iron(III) catalyst in hydrogen peroxide decomposition
    Terlecki-Baricevic, A.
    Cupic, Z.
    Anic, S.
    Kolar-Anic, L.
    Journal of the Serbian Chemical Society,
  • [4] Oxidation of benzaldehyde to benzoic acid with aqueous hydrogen peroxide over dodecatungstophosphoric acid
    Huang, Qiuying
    Dong, Beibei
    Zheng, Xiucheng
    ADVANCES IN CHEMICAL ENGINEERING III, PTS 1-4, 2013, 781-784 : 219 - +
  • [5] PHOTOINDUCED OXIDATION OF BENZOIC-ACID WITH AQUEOUS HYDROGEN-PEROXIDE
    OGATA, Y
    TOMIZAWA, K
    YAMASHITA, Y
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (04): : 616 - 619
  • [6] Iron catalyst supported on modified kaolin for catalytic wet peroxide oxidation
    Boukhemkhem, Ali
    Rida, Kamel
    Pizarro, Alejandro H.
    Molina, Carmen B.
    Rodriguez, Juan J.
    CLAY MINERALS, 2019, 54 (01) : 67 - 73
  • [7] Use of an amorphous iron oxide hydrated as catalyst for hydrogen peroxide oxidation of ferulic acid in water
    Andreozzi, Roberto
    Canterino, Marisa
    Caprio, Vincenzo
    Di Somma, Ilaria
    Marotta, Raffaele
    JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (02) : 870 - 875
  • [8] Hydrogen Peroxide Oxidation of Hydrocarbons Catalyzed by a Silica Supported Iron Precursor
    Hassan H. Monfared
    Maryam Ghorbani
    Monatshefte für Chemie / Chemical Monthly, 2001, 132 : 989 - 992
  • [9] OXIDATION OF PHENOLS IN WATER BY HYDROGEN-PEROXIDE ON ALUMINE SUPPORTED IRON
    ALHAYEK, N
    DORE, M
    WATER RESEARCH, 1990, 24 (08) : 973 - 982
  • [10] Hydrogen peroxide oxidation of hydrocarbons catalyzed by a silica supported iron precursor
    Monfared, HH
    Ghorbani, M
    MONATSHEFTE FUR CHEMIE, 2001, 132 (08): : 989 - 992
12345