Molybdenum tin-containing π-complexes (R3SnCH=CH2)Mo(N-2,6-Pr2i-C6H3)(OCMe2CF3)2• Synthesis and catalytic properties

被引：2

作者：

Barinova, Yu. P. ^{[1
]}

Bochkarev, L. N. ^{[1
]}

Kurskii, Yu. A. ^{[1
]}

Abakumov, G. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2012年 / 82卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

IMIDO ALKYLIDENE COMPLEXES;

D O I：

10.1134/S1070363212010033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tin-containing molybdenum pi-complexes (R3SnCH=CH2)Mo(N-2,6-Pr (i) 2C6H3)(OCMe2CF3)(2) (R = Me, Et, Ph) were synthesized by reaction of PhMe2CCH=Mo(N-2,6-Pr (i) 2C6H3)(OCMe2CF3)(2) with organotin vinyl reagents R3SnCH=CH2. The structure of compounds I-III was determined by NMR spectroscopy. Complexes I-III are active initiators of the norbornene metathesis polymerization.

引用

页码：17 / 22

页数：6

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