Catalytic properties of superconductor-type cuprates in direct hydroxylation of phenol to diphenols

被引：0

作者：

Men, Y ^{[1
]}

Liu, Y ^{[1
]}

Li, J ^{[1
]}

Yang, XG ^{[1
]}

Wu, Y ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

ACTA CHIMICA SINICA | 2003年 / 61卷 / 04期

关键词：

superconductor-type cuprates; hydroxylation of phenol; mechanism;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of superconductor-type cuprates synthesized by citric acid complex method exhibited high catalytic activity in direct hydroxylation of phenol to diphenols. The relationship between catalytic activity and structure of catalysts was. investigated by means of chemical analysis and O-2-TPD. It was found that the average valence of copper and the contents of nonstoichiometric oxygen could be the key factors to control the hydroxylation activity of phenol and the decomposition activity of H2O2. The mechanism involving the role of electron transfer of quinones was also proposed.

引用

页码：547 / 550

页数：4

共 9 条

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