Systematic study of the standard transfer Gibbs energy of potassium tetrophenylborate from water to water and alcohol mixtures

被引：3
|
作者：
Cao, LX
Zhou, BX
Shi, PF
Zhou, LZ
机构：
[1] Harbin Inst Technol, Dept Nat Sci, Weihai 264200, Peoples R China
[2] Harbin Inst Technol, Dept Appl Chem, Harbin 150001, Peoples R China
[3] Yantai Teachers Coll, Dept Chem, Yantai 264025, Peoples R China
来源：
ACTA PHYSICO-CHIMICA SINICA | 2001年 / 17卷 / 06期
关键词：
standard transfer Gibbs energy; standard transfer Gibbs energy of cavity; standard transfer Gibbs energy of interaction; potassium tetrophenylborate;
D O I：
10.3866/PKU.WHXB20010619
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The standard transfer Gibbs energies (Delta (tr) G(o)) of KBPh4 from reference solvent of water to water/ethanol, water/propanol, water/2-propanol, water/ethylene glycol, water/glycerol mixtures in different proportional ratio have been studied. The interactions of KBPh4 with the above mixed solvents were analyzed. The standard transfer Gibbs energy of cavity(Delta (tr) G(cav)(o)) and the standard transfer Gibbs energy of interaction(Delta (.)(tr) G(o) (int)) from water to water/2-propanol mixtures at 298. 15 K were calculated by the Scaled Particle Theory (SPT).
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页码：565 / 569
页数：5
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