Preparation of Organo-Inorganic Hybrid Gel Based on Branched Polyethyleneimine Crosslinked with Polyethylene Glycol Diglycidyl Ether and Calcium Phosphate Oligomers

被引:1
|
作者
Wang, Ling [1 ]
Wang, Jun [1 ]
Song, Kao-ping [2 ]
Ding, Wei [1 ]
Lv, Man [1 ]
Pei, Yu [1 ]
Yang, Erlong [2 ]
机构
[1] Northeast Petr Univ, Coll Chem & Chem Engn, Prov Key Lab Polyolefin New Mat, Daqing 163318, Peoples R China
[2] Northeast Petr Univ, Key Lab Enhanced Oil & Gas Recovery, Minist Educ China, Daqing 163318, Peoples R China
关键词
Compendex;
D O I
10.1134/S1560090422700452
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
prepare a uniformly network structured stimulus-responsive copolymer, organic polyethylene imine (PEI), polyethylene glycol glycidyl ether (PEGO) and inorganic calcium phosphate oligomers (CPO) as precursors, were used to prepare the PEI-PEGO-CPO hydrogels. The structure and properties of the products were characterized using infrared, 1H NMR and swelling behavior tests. The influence of CPO on temperature and pH sensitivity of the hydrogels was systematically investigated. The hydrogels were switched at temperatures between 20 and 60 degrees C, pH values between 8 and 13. The results showed that the addition of CPO can effectively improve the temperature and pH responsive properties of the hydrogels. In addition, the hydrogels showed excellent reversibility for swelling-deswelling characteristics.
引用
收藏
页码:707 / 714
页数:8
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