A Direct Synthesis of Symmetrical (E,E)-1,4-Diaryl-1,3-butadienes by Wenkert Arylation of Thiophene

被引：15

作者：

Hintermann, Lukas ^{[1
]}

Schmitz, Marco ^{[2
]}

Chen, Yun ^{[2
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 14-15期

关键词：

alkenes; cross-coupling; homogeneous catalysis; nickel; sulfur heterocycles; CARBON-CARBON BONDS; NICKEL-INDUCED CONVERSION; ONE-STEP TRANSFORMATIONS; STEREOSELECTIVE-SYNTHESIS; GRIGNARD-REAGENTS; EUDIA-PAVONIA; HECK REACTION; OLEFINS; OXYGEN; COMPLEXES;

D O I：

10.1002/adsc.201000350

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The nickel-catalyzed coupling of thiophene with aryl Grignard reagents (Wenkert reaction) is accelerated by N-heterocyclic carbene or trialkylphosphane ligands, providing a general, scalable direct synthesis of symmetrical 1,4-diarylbutadienes.

引用

页码：2411 / 2415

页数：5

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