Infrared Spectra and Hydrogen-Bonded Network Structures of Large Protonated Water Clusters H+(H2O)n (n=20-200)

被引：85
|
作者：
Mizuse, Kenta [1 ]
Mikami, Naohiko [1 ]
Fujii, Asuka [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 52期
关键词：
density functional calculations; hydrogen bonds; IR spectroscopy; mass spectrometry; water chemistry; LIQUID WATER; ICE; SPECTROSCOPY; SURFACES; SIZE; SIGNATURES; (H2O)(N); H2O;
D O I：
10.1002/anie.201003662
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Precisely size-selected protonated water clusters H+(H 2O)n (n=20-200) were studied by IR spectroscopy to provide insights into the structures of large-scale H-bonded water networks. The spectral features reveal that cluster structures gradually approach that of the bulk-water network and involve a greater number of four-coordinate water molecules with increasing cluster size (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10119 / 10122
页数：4
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