Synthesis and properties of nickel(11) complexes containing trimethylphosphine and thiophenolato-ligands

被引：5
|
作者：
Cao, Ruixia [1 ]
Li, Xiaoyan [1 ]
Sun, Hongjian [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 13-14期
关键词：
nickel; thiophenol; trimethylphosphine; crystal structure;
D O I：
10.1002/zaac.200700205
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of tbiophenols with [NiMe2(PMe3)(3)] yields thiophenolato nickel(II) complexes trans-[Ni(SAr)(2)(PMe3)(2)] (Ar = phenyl (1), 2-methylphenyl (2) and 4-methoxyphenyl (3)) with tetracoordinated nickel atoms. The molecular structures of I and 2 were determined by X-ray crystallography. The three complexes show trans square planar arrangement of the donor atoms. The mechanism of formation is proposed and discussed. In addition the intermediate methyl thiophenolato nickel(II) complex, [Ni(SAr)(PMe3)(2)Me] (Ar = phenyl) (4) was isolated in the case of thiophenol.
引用
收藏
页码：2305 / 2309
页数：5
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