Syntheses and structural characterization of the one dimensional polymers:: 1∞[Rh2(OAc)4(NCPhCN).S], S = CH3COCH3, CH3OH, C2H5OH, C4H8O and C6H6

被引：11

作者：

Niu, TY ^{[1
]}

Lu, J ^{[1
]}

Crisci, G ^{[1
]}

Jacobson, AJ ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

POLYHEDRON | 1998年 / 17卷 / 23-24期

基金：

美国国家科学基金会;

关键词：

coordination polymer; one dimensional polymer chains; dirhodiumtetraacetate; 1,4-dicyanobenzene; synthesis; crystal structure;

D O I：

10.1016/S0277-5387(98)00213-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and characterization of five compounds obtained by the reaction of dirhodium(II)tetraacetate with 1,4-dicyanobenzene in different solvent systems are described. The structures of Rh-2(OAc)(4)(NCPhCN). CH3COCH3 (1), Rh-2(OAc)(4)(NCPhCN). 2CH(3)OH (2), Rh-2(OAc)(4)(NCPhCN). C4H8O (4) and Rh-2(OAc)(4)(NCPhCN). C6H6 (5) were determined by single crystal X-ray diffraction. All structures contain one dimensional polymeric chain, comprised of dirhodiumtetraacetate units bridged by 1,4-dicyanobenzene molecules. Solvent molecules are located between the chains in each structure and three different packing arrangements of the polymer chains result from the inclusion of these different solvent molecules. Compounds 1, 2 and 3 crystallize in space group C2/c with similar cell parameters. Compound 4 also crystallizes in the same space group, but its structure is significantly different from those of 1, 2 and 3. Compound 5 crystallizes in space group P (1) over bar and contains an unusual polymer chain structure. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4079 / 4089

页数：11

共 50 条

[1] THE PROTON AFFINITY OF CH3OH AND C2H5OH MOLECULES
FRANKEVICH, EL
TALROZE, VL
ZHURNAL FIZICHESKOI KHIMII, 1959, 33 (05): : 1093 - 1099
[2] DFT study for the reactions of H atoms with CH3OH and C2H5OH
Carvalho, Edson F. V.
Barauna, Alessandra N.
Machado, Francisco B. C.
Roberto-Neto, Orlando
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2008, 108 (13) : 2476 - 2485
[3] Theoretical study on the kinetics for OH reactions with CH3OH and C2H5OH
Xu, Shucheng
Lin, M. C.
PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2007, 31 : 159 - 166
[4] FERROELECTRICITY IN 3C6H4(OH)2.CH3OH
MURAKAMI, E
KOMUKAE, M
OSAKA, T
MAKITA, Y
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1990, 59 (04) : 1147 - 1149
[5] GAS-PHASE SOLVATION OF CL- WITH H2O, CH3OH, C2H5OH, I-C3H7OH, N-C3H7OH, AND T-C4H9OH
HIRAOKA, K
MIZUSE, S
CHEMICAL PHYSICS, 1987, 118 (03) : 457 - 466
[6] ABINITIO PROTON AFFINITIES OF HCOOH, CH3COOH, CH3OH, AND C2H5OH
VONNAGYFELSOBUKI, EI
KIMURA, K
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (21): : 8041 - 8044
[7] THE STRUCTURE OF [VCL3(C4H8O)2(OH)].C4H8O
BOTTOMLEY, F
SUTIN, LC
WHITE, PS
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 529 - 531
[8] [30]metallacrown-10 compounds:: [Mn(C14H9N2O3)(CH3OH)]10•5CH2Cl2•6 CH3OH•H2O and [Fe(C14H9N2O3)(CH3OH)]10•3 CH2Cl2•12.5 CH3OH•5 H2O
Liu, SX
Lin, S
Lin, BZ
Lin, CC
Huang, JQ
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (06) : 1084 - +
[9] SPECTROSCOPIC STUDIES CONCERNING STRUCTURE AND THERMODYNAMIC BEHAVIOUR OF H2O CH3OH AND C2H5OH
LUCK, WAP
DISCUSSIONS OF THE FARADAY SOCIETY, 1967, (43): : 115 - &
[10] COMPRESSIBILITIES AND ISOCHORES OF (C3F7COOCH2)4C, C-SI4O4(CH3)8, N-C5H12,N-C8H18, 2,2,4-C5H9(CH3)3, C-C5H10, C-C6H12, C-C6H11CH3, C6H5CH3, P-C6H4(CH3)2, S-C6H3(CH3)3, CH2CL2
SHINODA, K
HILDEBRAND, JH
JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (01): : 183 - &

← 1 2 3 4 5 →