Synthesis of magnetic 4A zeolite at ultrasonic condition

被引:3
|
作者
Cao Ji-Lin [1 ]
Xing Dong-Qiang [1 ]
Liu Xiu-Wu [1 ]
Tan Zhao-Yang [1 ]
机构
[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
关键词
ultrasonic; magnetic 4A zeolite; adsorption; hydrothermal method;
D O I
10.3866/PKU.WHXB20071212
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to solve the difficulty in separating powdery 4A zeolite from solution in application of 4A zeolite, a series of magnetic 4A zeolites with different Fe3O4 contents were synthesized by traditional hydrothermal method through ultrasonic crystallization for 6 It at 70 degrees C after adding magnetic Fe,04 particulates to the crystallization solution for 4A zeolite synthesis. The products were characterized by X-ray diffraction (XRD), scanning electron rnicroscopy (SEM), IR, magnetic susceptibility, TG/DTA, EDX and ion exchange capability. The results showed that the magnetic 4A zeolite had good magnetism and its magnetic susceptibility increased with the Fe3O4 amount increasing. For adsorption of F- and Cr (VI) in water, the adsorption capability of magnetic 4A zeolite is equal with the pure 4A zeolite and the adsorption rate filled well the pseudo-second-order rate model.
引用
收藏
页码:1893 / 1898
页数:6
相关论文
共 15 条
  • [1] Effects of ultrasound on zeolite A synthesis
    Andaç, Ö
    Tatlier, M
    Sirkecioglu, A
    Ece, I
    Erdem-Senatalar, A
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 79 (1-3) : 225 - 233
  • [2] Removal of heavy metal ions by carrier magnetic separation of adsorptive particulates
    Feng, D
    Aldrich, C
    Tan, H
    [J]. HYDROMETALLURGY, 2000, 56 (03) : 359 - 368
  • [3] HENGLEIN A, 1995, ULTRASON SONOCHEM, V2, P115
  • [4] Homer John, 1995, ULTRASON SONOCHEM, V2, P71
  • [5] Structures and magnetic susceptibility of Ni-ion-introduced zeolite A and X
    Horikawa, Y
    Ohnishi, N
    Hiraga, K
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1996, 217 : 139 - 141
  • [6] JEONG C, 2005, AICHE SPRING NAT M A, P37
  • [7] Preparation and properties of novel magnetic Fe3O4/EDTA nano-composite particles
    Jiang, W
    Li, FS
    Chen, LY
    Yang, Y
    Chu, JJ
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2005, 21 (02) : 182 - 186
  • [8] Li C.x., 2001, SHIYOU XUEBAO SHIYOU, V17, P86
  • [9] [林本兰 LIN Benlan], 2007, [材料科学与工程学报, Journal of materials Science and engineering], V25, P88
  • [10] Liu SX, 2002, NEW CARBON MATER, V17, P45