The first RuIIPdII2S3 metallochelate ring formed on a [Ru(bpy)2]2+ core

被引：3

作者：

Yoshimura, T ^{[1
]}

Shinohara, A

Hirotsu, M

Konno, T

机构：

[1] Osaka Univ, Dept Chem, Grad Sch Sci, Toyonaka, Osaka 5600043, Japan

[2] Osaka City Univ, Dept Mat Sci, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 10期

关键词：

D O I：

10.1246/cl.2005.1310

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1:2 reaction of [RuCl2(bpy)(2)] (bpy = 2,2'-bipyridine) with [Pd(aet)(2)] (aet = 2-aminoethanethiolate) led to the formation of [Ru(bpy)(2) {Pd-2(aet)(3)} {Pd(aet)(2))](3+) ([1](3+)), which was converted into [Ru(bpy)(2){Pd(aet)(3)} {Pd(aet)(2-aminoethanesulfenato)}](3+) ([1'](3+)) and [Ru(bpy)(2)[Pd-2(aet)(3)Cl}](2+) ([2](2+)) having a six-membered RuPd2S3 metallochelate ring.

引用

页码：1310 / 1311

页数：2

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