Rhodium(III)-Catalyzed One-Pot Cascade Synthesis of Functionalized Isoquinolines

被引：18

作者：

Wu, Xiao-Lin ^{[1
]}

Dong, Lin ^{[1
]}

机构：

[1] Sichuan Univ, West China Sch Pharm, Key Lab Drug Targeting & Drug Delivery Syst, Educ Minist, Chengdu 610041, Sichuan, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 12期

关键词：

alkenes; rhodium; domino reactions; C-H activation; 2H-imidazoles; PALLADIUM-CATALYZED IMINOANNULATION; H BOND FUNCTIONALIZATION; REGIOSELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; AROMATIC KETIMINES; CARDIOTONIC AGENTS; COUPLING REACTIONS; NATURAL-PRODUCTS; 4+2 ANNULATION; ALKYNES;

D O I：

10.1002/ajoc.201800459

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient Rh(III)-catalyzed one-pot reaction for the synthesis of functionalized alpha-carbonyl isoquinolines from 2H-imidazoles and alkenes has been successfully developed. This type of structure is constructed by using a transition-metal-catalyzed cascade: C-H bond activation, alkenylation, annulation, and hydrolysis.

引用

页码：2422 / 2426

页数：5

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