Recent Advances in Metal-Catalyzed C-H Bond Functionalization Reactions of Sulfoxonium Ylides

被引：32
|
作者：
Bhorali, Pratiksha [1 ,2 ]
Sultana, Sabera [1 ]
Gogoi, Sanjib [1 ,2 ]
机构：
[1] CSIR, North East Inst Sci & Technol, Appl Organ Chem Chem Sci & Technol Div, Jorhat 785006, Assam, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 04期
关键词：
sulfoxonium ylide; metal-catalyzed; carbene precursor; C-H bond functionalization; heterocycles and carbocycles; INSERTION REACTIONS; RHODIUM(III)-CATALYZED ANNULATION; DIMETHYLSULFONIUM METHYLIDE; ACTIVATION; INDOLES; SALICYLALDEHYDES; ACYLMETHYLATION; CONSTRUCTION; DIMERIZATION; DERIVATIVES;
D O I：
10.1002/ajoc.202100754
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In recent years, the transition-metal-catalyzed functionalization reactions of sulfoxonium ylides have been explored extensively because of their usefulness as carbene-transfer agents, since they can produce metal carbenes through metal catalysis. Moreover, they are safer and have the advantages of simple handling and good stability over their other counterparts like diazo-compounds. This review article attempts to highlight the recent advances in the metal-catalyzed C-H functionalization of sulfoxonium ylides.
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页数：20
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