TiO2 Photoanode Structure with Gradations in V Concentration for Dye-Sensitized Solar Cells

被引:51
|
作者
Liu, Zhifeng [1 ]
Li, Yabin [1 ]
Liu, Chengcheng [1 ]
Ya, Jing [1 ]
Lei, E. [1 ]
Zhao, Wei [1 ]
Zhao, Dan [1 ]
An, Li [1 ]
机构
[1] Tianjin Inst Urban Construct, Dept Mat Sci & Engn, Tianjin 300384, Peoples R China
基金
中国博士后科学基金;
关键词
V-TiO2; photoanode; gradient; V doping; dye-sensitized solar cell; NANOTUBE ARRAYS; GEL METHOD; FILMS; EFFICIENCY; ELECTRODE; ENHANCE; SURFACE;
D O I
10.1021/am200232g
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
V-TiO2(GC) photoanode film with graduated structure was prepared in a dye-sensitized solar cell work electrode by layer-by-layer method using TiO2 precursor with gradations in V concentration on the indium tin oxide transparent conducting glass from substrate to surface. The effects of the gradient in V concentration on the structures and properties of TiO2 photoanode film were discussed. The structure of the gradient V concentration has remarkable influence on the final performance of the DSSCs and I-V characteristic measurement indicates an enhanced efficiency by 31% as compared to pure TiO2 nanoparticles film samples due to abundant solar light, fast injection and photoexcited electrons, simultaneously. transmission velocity and the slowdown recombination of photoexcited electrons, simultaneously.
引用
收藏
页码:1721 / 1725
页数:5
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