Locked π-expanded chlorins in two steps from simple tetraarylporphyrins

被引：26

作者：

Fouchet, J ^{[1
]}

Jeandon, C ^{[1
]}

Ruppert, R ^{[1
]}

Callot, HJ ^{[1
]}

机构：

[1] Univ Strasbourg 1, CNRS, UMR 7177, Fac Chim, F-67000 Strasbourg, France

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 23期

关键词：

D O I：

10.1021/ol052103y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Upon tandem Reformatsky reaction, easily accessible porphyrinic ketones give "locked" chlorinic diester. Both ketones and diesters, as bases or palladium complexes, efficiently generate singlet dioxygen, as demonstrated by trapping with cholesterol.

引用

页码：5257 / 5260

页数：4

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