Stereoconvergent approach to each of the stereoisomeric hydroxydiquinanes based on the anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols

被引:3
|
作者
Hashimoto, H
Seki, K
Ueno, M
Sato, T
Uyehara, T [1 ]
机构
[1] Utsunomiya Univ, Fac Engn, Dept Appl Chem, Utsunomiya, Tochigi 3218585, Japan
[2] Tohoku Univ, Fac Sci, Instrumental Anal Ctr Chem, Sendai, Miyagi 9808578, Japan
关键词
rearrangements; carbanions; potassium and compounds; solvents and solvent effects;
D O I
10.1016/S0040-4039(98)02389-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The anionic [1,3] rearrangement of both stereoisomeric bicyclo[3.2.1]oct-6-en-2-ols by treatment with KN(TMS)(2) in toluene or in diglyme took place as a stereoconvergent route giving each of the stereoisomeric hydroxydiquinanes. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
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页码:511 / 514
页数:4
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