Universal character of relaxation of the intensity of light scattering by boron oxide melt in the temperature range 300-340A°C

被引:3
|
作者
Bokov, N. A. [1 ]
机构
[1] Russian Acad Sci, Grebenshchikov Inst Silicate Chem, Nab Makarova 2, St Petersburg 199034, Russia
关键词
boron oxide; light scattering; relaxation;
D O I
10.1134/S1087659616060031
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
It has been established that the process of stabilization of the boron oxide melt in the temperature range 300-340A degrees D is accompanied by universal changes in the intensity of the polarized V (v) component of light scattering characterized with the formation of a minimum. It has been demonstrated that the above feature does not depend on the direction of the intensity approaching to the stationary state for the selected temperature; i.e., it is observed in the process of intensity relaxation from both high and low temperatures. Upon attainment of the minimal values, the increase of the V (v) intensity with the stabilization time was found to be satisfactorily described by the empirical dependence of the exponential type. The characteristic times of intensity changes calculated in accordance with the respective equation significantly exceed the times of structural relaxation and increase along with the temperature decrease in accordance with the exponential dependence. It has been established that the characteristic times of intensity changes as its values approach the stationary one from a higher temperature are larger than when approaching from a lower temperature. It has been shown that under these conditions, changes in the intensity of the depolarized H (v) component are characterized with the formation of a maximum registered for both modes (sample cooling and heating). It has been revealed that the increase of the H (v) intensity in the maximum does not exceed 10% of its regular value, which allows relating the formation of a minimum of the V (v) component to the decrease of the isotropic light scattering intensity.
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页码:525 / 529
页数:5
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