Catalytic Hydroxylation of Phenol by Co(II) and Ni(II) Complexes of An Tetraaza Macrocyclic Crown Ether

被引：0
|
作者：
Bi, Jian-Hong [1 ]
Yao, Zi-Lu [2 ]
Cui, Man [3 ]
机构：
[1] Hefei Normal Univ, Dept Chem & Chem Engn, Hefei, Peoples R China
[2] Henan Polytech Univ, Sch Mat Sci & Engn, Dept Chem Engn & Technol, Jiaozuo 454003, Peoples R China
[3] Shuangdun Middle Sch, Hefei 231131, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Azamacrocyclic crown ether; Co(II); Ni(II); Complexes; Catalyst; Phenol; hydroxylation; Diphenol; CU;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic abilities of the two tetraaza macrocyclic crown ether complexes of Co(II) and Ni(II) with composition CoL(ClO4)(2) and NiL(ClO4)(2) in the hydroxylation of phenol with H2O2 was studied. When CoL(ClO4)(2) was used as catalysts, 4.6 To phenol conversion was obtained with, 87.5 % selectivity to diphenol. But when NiL(ClO4)(2) was used as catalysts, 5.7 % phenol conversion was obtained with 80.8 % selectivity to diphenol under the optimum reaction conditions.
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页码：935 / 936
页数：2
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