Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3- by mild, non-aqueous reductive aggregation

被引：24

作者：

Bakri, Ridla ^{[1
]}

Booth, Andrew ^{[1
]}

Harle, Gavin ^{[1
]}

Middleton, Paul S. ^{[1
]}

Wills, Corinne ^{[1
]}

Clegg, William ^{[1
]}

Harrington, Ross W. ^{[1
]}

Errington, R. John ^{[1
]}

机构：

[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

BOND-VALENCE PARAMETERS; RAY CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESES; BUILDING-BLOCKS; FRAMEWORKS; POLYANION; CLUSTERS; MOLYBDOVANADATE; SYSTEMS; SOLIDS;

D O I：

10.1039/c2cc17670j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled reductive assembly of capped Keggin anions [PMo12O40-(MLm)(n)](3-) has been achieved by reduction of [PMo12O40](3-) with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40{Co(MeCN)(2)}](3-) and bi-capped [PMo12O40(VO)(2)](3-) and [PMo12O40Sb2](3-)

引用

页码：2779 / 2781

页数：3

共 20 条

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Hu, J
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JOURNAL OF CATALYSIS, 2000, 195 (02) : 360 - 375
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II'In V.G.
Theoretical and Experimental Chemistry, 1998, 34 (3) : 165 - 171
[5] Compounds of [PMo12O40]3- anion with cationic surfactants forming nanoperiodic structure
Filippov, OP
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TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA, 1998, 34 (03): : 184 - 190
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Nakashima, Y
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Kitazumi, I
Himeno, S
ELECTROPHORESIS, 2001, 22 (16) : 3377 - 3381
[7] A New Supramolecular Compound Based on Cd(II)-Schiff-base and Keggin-type [PMo12O40]3-
Wei Mei-Lin
Sun Rui-Ping
Zhuang Peng-Fei
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (11) : 1646 - 1651
[8] Keggin-Type Polyoxometalate ([PMo12O40]3-) in Radical Initiating Systems: Application to Radical and Cationic Photopolymerization Reactions
Xiao, Pu
Dumur, Frederic
Tehfe, Mohamad-Ali
Graff, Bernadette
Fouassier, Jean Pierre
Gigmes, Didier
Lalevee, Jacques
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (15) : 1749 - 1755
[9] A new supramolecular compound based on Mn(II)-Schiff-base and Keggin-type [PMo12O40]3-
Wei, M. L.
Zhuang, P. F.
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RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (01) : 30 - 35
[10] Two new supramolecular compounds based on Ni(II)-Schiff-base and Keggin-type [PMo12O40]3-
Wei, Meilin
Zhuang, Pengfei
Sun, Ruiping
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (19) : 3384 - 3392

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