Isomeric heteroligand platinum(II) complexes with amino acids of the glycine series

被引：0

作者：

Krylova, LF ^{[1
]}

Pavlushko, TA ^{[1
]}

机构：

[1] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 46卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heteroligand bis-chelates trans-[PtLL'] (L' = Gly; L = Ala (I), Am (II), Val (III); L' = Am; L = Val (IV)), cis-[Pt(Val)(PhAla)] (V) and heteroligand dichloro complexes trans-[Pt(LH)(L'H)Cl-2] (L'H = GlyH; LH = AlaH (VI), AmH (VII), ValH (VIII); L'H = AmH; LH = ValH (IX)) and cis-[Ph(ValH)(PhAlaH)Cl-2] (X) were synthesized and isolated in a pure state. The structure of the complexes was studied by Pt-195 and H-1 NMR. Two variants of H-1 NMR spectroscopy were used, 1D and H-1-H-1 COSY 2D spectroscopy. Compounds IV, V, and X were shown to exist as two diastereomers. The mechanism of the synthesis of heteroligand cis and trans isomers of Pt(II) complexes in aqueous solutions was studied by Pt-195 NMR.

引用

页码：827 / 837

页数：11

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