Carbon-Based Catalysts for Biodiesel Production-A Review

被引:37
|
作者
Clohessy, Jack [1 ]
Kwapinski, Witold [1 ]
机构
[1] Univ Limerick, Bernal Inst, Dept Chem Sci, Limerick V94 T9PX, Ireland
来源
APPLIED SCIENCES-BASEL | 2020年 / 10卷 / 03期
关键词
heterogeneous acid catalyst; biofuel; transesterification; carbohydrate; biomass; biochar; SOLID ACID CATALYST; FREE FATTY-ACID; HETEROGENEOUS CATALYSTS; EFFICIENT PRODUCTION; SOYBEAN OIL; TRANSESTERIFICATION; ESTERIFICATION; BIOCHAR; WASTE; CONVERSION;
D O I
10.3390/app10030918
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In recent years, a new class of superior heterogeneous acid catalyst for biodiesel production has emerged. These catalysts offer advantages over their predecessors such as high surface area, elevated acid site density, enhanced catalyst activity, good operation stability and relevant economic affordability in an environmentally friendly frame. This review was concerned with carbon-based solid acid (CBAS) catalysts derived from both carbohydrate and pyrolysis products. A series of CBASs with various origins such as D-glucose, sucrose, starch, cellulose and vegetable oil asphalt, converted to char and sulphonated, have been explored as potential heterogeneous catalysts. Catalyst preparation and synthesis methods were briefly summarized. Catalyst characterization and performance for biofuels related reactions were elucidated, identifying potential research applications. Three catalysts in particular were identified as having potential for industrial application and requiring further research.
引用
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页数:17
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