Terahertz vibration-rotation-tunneling spectroscopy of the water tetramer-d8: Combined analysis of vibrational bands at 4.1 and 2.0 THz

被引：12

作者：

Lin, Wei ^{[1
]}

Han, Jia-Xiang ^{[1
]}

Takahashi, Lynelle K. ^{[1
]}

Harker, Heather A. ^{[1
]}

Keutsch, Frank N. ^{[1
]}

Saykally, Richard J. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2008年 / 128卷 / 09期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1063/1.2837466

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the measurement of terahertz vibration-rotation-tunneling spectra of (D2O)(4) in the spectral region near 4.13 THz. The characterization of this perpendicular band extends a previously reported study [J. Chem. Phys. 111, 7801 (1999)]. We observed 239 new transitions, each being split into a doublet of constant (approximately 192 MHz) spacing. These are included in a combined fit with the 113 previously measured transitions of the 2.03 THz parallel band using an effective Hamiltonian similar to that used in the global fit of the water trimer. The detailed understanding of the water tetramer evolving from this work underlies our efforts to quantify the contribution of many-body forces to the hydrogen bonding interactions in condensed phase water. (c) 2008 American Institute of Physics.

引用

页数：10

共 8 条

[1] The far-infrared vibration-rotation-tunneling spectrum of the water tetramer-d8
Cruzan, JD
Brown, MG
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Braly, LB
Saykally, RJ
JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (16): : 6634 - 6644
[2] Terahertz laser vibration-rotation tunneling spectroscopy of the water tetramer
Cruzan, JD
Viant, MR
Brown, MG
Saykally, RJ
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (48): : 9022 - 9031
[3] Terahertz vibration-rotation-tunneling spectroscopy of water clusters in the translational band region of liquid water
Keutsch, FN
Brown, MG
Petersen, PB
Saykally, RJ
Geleijns, M
van der Avoird, A
JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (09): : 3994 - 4004
[4] Terahertz vibration-rotation-tunneling (VRT) spectroscopy of the d6-water trimer:: Complete characterization of the 2.94 THz torsional band (kn = ±21←00)
Han, Jia-xiang
Takahashi, Lynelle K.
Lin, Wei
Lee, Eddy
Keutsch, Frank N.
Saykally, Richard J.
CHEMICAL PHYSICS LETTERS, 2006, 423 (4-6) : 344 - 351
[5] Terahertz laser vibration-rotation-tunneling spectrum of the water pentamer-d10.: Constraints on the bifurcation tunneling dynamics
Cruzan, JD
Viant, MR
Brown, MG
Lucas, DD
Liu, K
Saykally, RJ
CHEMICAL PHYSICS LETTERS, 1998, 292 (4-6) : 667 - 676
[6] Terahertz vibration-rotation-tunneling spectroscopy of the propane-water dimer: The ortho-state of a 20 cm-1 torsion
Lin, Wei
Steyert, David W.
Hlavacek, Nikolaus C.
Mukhopadhyay, Anamika
Page, Ralph H.
Siegel, Peter H.
Saykally, Richard J.
CHEMICAL PHYSICS LETTERS, 2014, 612 : 167 - 171
[7] Terahertz vibration-rotation-tunneling spectroscopy of the propane-water dimer: The ortho-state of a 20 cm-1 torsion
Lin, Wei
Steyert, David W.
Hlavacek, Nikolaus C.
Mukhopadhyay, Anamika
Page, Ralph H.
Siegel, Peter H.
Saykally, Richard J.
Chemical Physics Letters, 2014, 612 : 167 - 171
[8] Terahertz vibration-rotation-tunneling spectroscopy of thepropane-water dimer: The ortho-state of a 20 cm-1 torsion
Saykally, Richard J. (saykally@berkeley.edu), 1600, Elsevier B.V., Netherlands (612):

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