An unusual cuprous iodide polymer incorporating I-, I2 and I3- structural units

被引：12
|
作者：
Hu, Jun [1 ]
Zhou, Jian [1 ]
Cao, Shumei [1 ]
机构：
[1] Chongqing Normal Univ, Coll Chem, Chongqing Key Lab Inorgan Funct Mat, Chongqing 401331, Peoples R China
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 48期
关键词：
RAY CRYSTAL-STRUCTURES; ORGANIC FRAMEWORKS; PHOTOLUMINESCENCE PROPERTIES; THERMOCHROMIC-LUMINESCENCE; ELECTRONIC-STRUCTURE; OXIDATIVE ADDITION; OPTICAL-PROPERTIES; COMPLEXES; LIGAND; COORDINATION;
D O I：
10.1039/c8dt04150d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel cuprous iodide polymer [Cu-2((4)-L)((2)-I-)(I-2)(I-3(-))](n)nI(2) (1, L = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized. 1 contains a 1-D chain [Cu-2((4)-L)((2)-I-)(I-2)(I-3(-))](n) and free I-2 molecules, which are interconnected by weak II interactions to form an unprecedented 3-D cuprous polyiodide network containing rare 1-D [(I-)2I(2)(I-3)(-)](n) polyiodide ribbons. 1 shows luminescence and photoelectronic properties, and its theoretical band structure was also studied.
引用
收藏
页码：17216 / 17220
页数：5
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