X-ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands.: Reactivity towards dioxygen

被引：13
|
作者：
Carré, F
Corriu, RJP
Lancelle-Beltran, E
Mehdi, A
Reyé, C
Guilard, R
Sykora, J
van der Lee, A
机构：
[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, CNRS, F-34095 Montpellier 5, France
[2] Univ Bourgogne, Lab Ingn Mol Separat & Applicat Gaz, LIMSAG, UMR 5633, F-21100 Dijon, France
[3] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague 6, Czech Republic
[4] Univ Montpellier 2, Inst Europeen Membranes, UMR 5635, CNRS, F-34095 Montpellier 5, France
来源：
DALTON TRANSACTIONS | 2003年 / 16期
关键词：
D O I：
10.1039/b304032a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(II) and cobalt(II) Schiff base complexes with derivatives of the pentadentate ligand bis(salicylideneimino-3-propyl)amine [H(2)salDPT] have been prepared. The X-ray crystal structures of the copper(II) complexes Cu[salDPT] and Cu[sal(n-propyltrimethylsilyl)DPT] were determined and revealed five-coordination at the metal centre in both cases. The 1:1 dioxygen adduct of Co[sal(n-propyltrimethylsilyl)DPT] was also isolated and its X-ray molecular structure determined.
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页码：3211 / 3215
页数：5
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