Citral hydrogenation on supported platinum catalysts

被引：59
|
作者：
Malathi, R [1 ]
Viswanath, RP [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Chennai 600036, India
来源：
APPLIED CATALYSIS A-GENERAL | 2001年 / 208卷 / 1-2期
关键词：
hydrogenation; citral; metal-support interaction; platinum; geraniol;
D O I：
10.1016/S0926-860X(00)00715-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Supported platinum systems have been used as catalysts for selective hydrogenation of citral to the unsaturated alcohol. The C=O bond is hydrogenated rather than the thermodynamically favorable C=C bond on supported platinum systems. This is due to the influence of the SMSI (strong metal-support interaction) state in these supported platinum catalysts. In all the supported catalyst systems the formation of geraniol (E isomer) has been observed as the sole product of the hydrogenation of citral. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：323 / 327
页数：5
相关论文
共 50 条
  • [1] Hydrogenation of Citral Over Carbon Supported Iridium Catalysts
    Bernas, Heidi
    Simakova, Irina
    Prosvirin, Igor P.
    Maki-Arvela, Paivi
    Leino, Reko
    Murzin, Dmitry Yu.
    CATALYSIS LETTERS, 2012, 142 (06) : 690 - 697
  • [2] Outstanding performances of magnesia-supported platinum-tin catalysts for citral selective hydrogenation
    Recchia, S
    Dossi, C
    Poli, N
    Fusi, A
    Sordelli, L
    Psaro, R
    JOURNAL OF CATALYSIS, 1999, 184 (01) : 1 - 4
  • [3] Catalysts Supported on Carbon Materials for the Selective Hydrogenation of Citral
    Bailon-Garcia, Esther
    Maldonado-Hodar, Francisco J.
    Perez-Cadenas, Agustin F.
    Carrasco-Marin, Francisco
    CATALYSTS, 2013, 3 (04) : 853 - 877
  • [4] HYDROGENATION OF CINNAMALDEHYDE AND CITRAL OVER RU SUPPORTED CATALYSTS
    GALVAGNO, S
    MILONE, C
    NERI, G
    DONATO, A
    PIETROPAOLO, R
    HETEROGENEOUS CATALYSIS AND FINE CHEMICALS III, 1993, 78 : 163 - 170
  • [5] Hydrogenation of Citral Over Carbon Supported Iridium Catalysts
    Heidi Bernas
    Irina Simakova
    Igor P. Prosvirin
    Päivi Mäki-Arvela
    Reko Leino
    Dmitry Yu. Murzin
    Catalysis Letters, 2012, 142 : 690 - 697
  • [6] HYDROGENATION OF BENZENE ON SUPPORTED PLATINUM CATALYSTS
    RATNASAM.P
    JOURNAL OF CATALYSIS, 1973, 31 (03) : 466 - 468
  • [7] Supported ionic liquids catalysts for fine chemicals: citral hydrogenation
    Mikkola, JP
    Virtanen, P
    Karhu, H
    Salmi, T
    Murzin, DY
    GREEN CHEMISTRY, 2006, 8 (02) : 197 - 205
  • [8] Silica Supported Bimetallic Catalysts for Liquid Phase Selective Hydrogenation of Citral
    Ananthan, S. A.
    Narayanan, V.
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (05) : 2115 - 2120
  • [9] TOLUENE HYDROGENATION OVER SUPPORTED PLATINUM CATALYSTS
    LIN, SD
    VANNICE, MA
    HERRMANN, JM
    WANG, D
    APESTEQUIA, C
    DUPREZ, D
    FIGUERAS, F
    CONNER, WC
    KIPERMAN, SL
    HALL, WK
    BLACKMOND, DG
    GRUNERT, W
    BUTT, JB
    SCHULZ, H
    STUDIES IN SURFACE SCIENCE AND CATALYSIS, 1993, 75 : 861 - 874
  • [10] SUPPORTED PALLADIUM AND PLATINUM AS CATALYSTS FOR HYDROGENATION OF CYCLOHEXENE
    BOUDART, M
    MADON, RJ
    GONZO, E
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, : 25 - 25
12345