Chiral halogen and chalcogen bonding receptors for discrimination of stereo- and geometric dicarboxylate isomers in aqueous media

被引:52
|
作者
Lim, Jason Y. C. [1 ]
Marques, Igor [2 ]
Felix, Vitor [2 ]
Beer, Paul D. [1 ]
机构
[1] Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England
[2] Univ Aveiro, CICECO Aveiro Inst Mat, Dept Chem, P-3810193 Aveiro, Portugal
关键词
RECOGNITION; DINUCLEAR; GLUTAMATE;
D O I
10.1039/c8cc06400h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel chiral halogen and chalcogen bonding receptors exhibit different selectivities for stereo- and geometric dicarboxylate isomers compared to a hydrogen bonding analogue. The unique geometric and electronic properties of the chalcogen bonding receptor facilitate the diagnostic fluorescence sensing of geometric dicarboxylate isomer guest species.
引用
收藏
页码:10851 / 10854
页数:4
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