3-Methyl-1,5-dinitro-9-phenacyl-3-azabicyclo[3.3.1]non-7-en-6-one

被引:0
|
作者
Borbulevych, OY [1 ]
Shahkheldyan, IV
Leonova, OV
Atroshchenko, YM
Alifanova, EN
机构
[1] New Mexico Highlands Univ, Dept Chem, Las Vegas, NM 87701 USA
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[3] LN Tolstoi Tula State Pedag Univ, Tula 300600, Russia
关键词
D O I
10.1107/S160053680202041X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
There are two molecules, A and B, in the asymmetric unit of the title compound, C34H34N6O12. In both molecules, the eight-membered ring has a conformation which is close to a boat-boat conformation and the cyclohexene ring is characterized by a sofa conformation. The nitro groups in each molecule are situated in equatorial positions. Both nitro groups of molecule A are considerably rotated with respect to the flattened fragment of the cyclohexene ring. The same is true for one of the nitro groups of molecule B, whereas the other such group in molecule B is almost coplanar with the corresponding fragment.
引用
收藏
页码:O1363 / O1364
页数:2
相关论文
共 50 条
  • [1] 3-methyl-1,5-dinitro-3-azabicyclo[3.3.1]non-7-ene
    Shishkin, OV
    Atroschenko, YM
    Gitis, SS
    Alifanova, EN
    Shakhkeldyan, IV
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 271 - 273
  • [2] 3-Methyl-1,5-dinitro-3-azabicyclo[3.3.1]non-7-ene
    A. N. Nesmeyanov Inst of, Organoelement Compounds of the, Russian Acad of Sciences, Moscow, Russia
    Acta Crystallogr Sect C Cryst Struct Commun, pt 2 (271-273):
  • [3] Reactions of 8-methyl-5-methylsulfanylmethyl-3-thiabicyclo-[3.3.1]non-7-en-6-one at the carbonyl group
    Baeva, L. A.
    Ulendeeva, A. D.
    Fatykhov, A. A.
    Lyapina, N. K.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 46 (07) : 1066 - 1069
  • [4] Reactions of 8-methyl-5-methylsulfanylmethyl-3-thiabicyclo-[3.3.1]non-7-en-6-one at the carbonyl group
    L. A. Baeva
    A. D. Ulendeeva
    A. A. Fatykhov
    N. K. Lyapina
    Russian Journal of Organic Chemistry, 2010, 46 : 1066 - 1069
  • [5] 3-Azabicyclo[3.3.1]nonane Derivatives: V. Synthesis of 7-Polyfluoroalkoxy-1,5-dinitro-3-azabicyclo[3.3.1]non-6-enes
    E. G. Nikiforova
    M. A. Korolev
    I. V. Shakhkel'dyan
    M. D. Dutov
    Yu. D. Grudtsyn
    Yu. M. Atroshchenko
    S. A. Shevelev
    V. A. Subbotin
    Russian Journal of Organic Chemistry, 2001, 37 : 734 - 738
  • [6] 3-azabicyclo[3.3.1]nonane derivatives: V. Synthesis of 7-polyfluoroalkoxy-1,5-dinitro-3-azabicyclo [3.3.1]non-6-enes
    Nikiforova, EG
    Korolev, MA
    Shakhkel'dyan, IV
    Dutov, MD
    Grudtsyn, YD
    Atroshchenko, YM
    Shevelev, SA
    Subbotin, VA
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 37 (05) : 734 - 738
  • [7] Synthesis of 1,5-dinitro-3-azabicyclo[3.3.1]non-6-ene derivatives
    Atroshchenko, YM
    Nikiforova, EG
    Gitis, SS
    Grudtsyn, YD
    Shishkin, OV
    Andrianov, VF
    Shakhkeldyan, IV
    ZHURNAL ORGANICHESKOI KHIMII, 1999, 35 (09): : 1339 - 1343
  • [8] Study of the bromination of 1,5-dinitro-3-azabicyclo-[3.3.1]non-6-enes
    I. V. Shakhkeldyan
    Yu. M. Atroshchenko
    N. K. Melekhina
    I. E. Yakunina
    K. I. Kobrakov
    A. N. Shumsky
    Chemistry of Heterocyclic Compounds, 2008, 44 : 690 - 699
  • [9] Chlorination features of 1,5-dinitro-3-azabicyclo[3.3.1]non-6-enes
    Yu. M. Atroshchenko
    N. K. Melekhina
    I. V. Shakhkel’dyan
    I. E. Yakunina
    A. N. Shchukin
    E. V. Shuvalova
    V. A. Subbotin
    Russian Journal of Organic Chemistry, 2006, 42 : 1220 - 1224
  • [10] STUDY OF THE BROMINATION OF 1,5-DINITRO-3-AZABICYCLO[3.3.1]NON-6-ENES
    Shakhkeldyan, I. V.
    Atroshchenko, Yu. M.
    Melekhina, N. K.
    Yakunina, I. E.
    Kobrakov, K. I.
    Shumsky, A. N.
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2008, 44 (06) : 690 - 699