Solubility of β-carotene in binary solvents formed by some hydrocarbons with tert-butyl methyl ether and with tert-amyl methyl ether

被引:3
|
作者
Treszczanowicz, T
Kasprzycka-Guttmans, T
Treszczanowicz, AJ
机构
[1] Polish Acad Sci, Inst Phys Chem, Supramol Chem Dept, Warsaw 42, Poland
[2] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland
[3] Natl Publ Hlth Inst, PL-00725 Warsaw, Poland
来源
关键词
D O I
10.1021/je0495583
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental results are reported for the solubility of beta-carotene in six binary mixed solvents formed by tert-butyl methyl ether or tert-amyl methyl ether with cyclohexane, hexane, and toluene at 293.15 K. A spectral colorimeter was used for the analysis of P-carotene concentration. The beta-carotene solubility in the pure solvents increases in the order hexane < tert-butyl methyl ether < tert-amyl methyl ether < cyclohexane < toluene. The solubility data as a function of the binary solvent mole fractions were correlated by the Myers and Scott equation. Results of these measurements were used to test the predictive ability of beta-carotene solubility in the binary mixed solvents using the Treszczanowicz and the Acree and Rytting models. Both models qualitatively predict the solubility of beta-carotene in the above-mentioned mixed solvents.
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页码:973 / 976
页数:4
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