Effect of the Cu content and ZnS treatment on the characteristics of synthesized ZnS:(Cu, Cl) electroluminescent phosphors

被引:10
|
作者
Sychov, M. M. [1 ]
Ogurtsov, K. A. [1 ]
Lebedev, V. T. [2 ]
Kulvelis, Yu V. [2 ]
Torok, Gy [3 ]
Sokolov, A. E. [2 ]
Trunov, V. A. [2 ]
Bakhmetyev, V. V. [1 ]
Kotomin, A. A. [1 ]
Dushenok, S. A. [1 ]
Kozlov, A. S. [1 ]
机构
[1] Tech Univ, St Petersburg State Inst Technol, St Petersburg 190013, Russia
[2] Russian Acad Sci, Konstantinov Petersburg Nucl Phys Inst, Gatchina 188300, Leningrad Oblas, Russia
[3] Hungarian Acad Sci, Wigner Res Ctr Phys, Res Inst Solid State Phys & Opt, Budapest, Hungary
关键词
Luminescence Spectrum; Zinc Sulfide; Accelerate Electron; Copper Sulfide; Nitrogen Plasma;
D O I
10.1134/S1063782612050223
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The effect of the pretreatment of ZnS via different methods on the characteristics of synthesized ZnS:(Cu, Cl) electroluminescent phosphors with varying concentrations of the activator dopant (Cu) is studied. As a result of the pretreatment of ZnS with accelerated electrons and in nitrogen plasma, an increase in the emission brightness of the synthesized phosphor and a shift of the luminescence spectrum to longer wavelengths are observed. These effects are attributed with increase in content of the activator in the phosphor matrix because of the formation of extra defects in the ZnS structure during treatment. In the case of shockwave treatment of ZnS, the generation of defects is not compensated by heat treatment during synthesis of the phosphor, and a positive enhanced-brightness effect is not attained.
引用
收藏
页码:696 / 700
页数:5
相关论文
共 50 条
  • [1] Effect of the Cu content and ZnS treatment on the characteristics of synthesized ZnS:(Cu, Cl) electroluminescent phosphors
    M. M. Sychov
    K. A. Ogurtsov
    V. T. Lebedev
    Yu. V. Kulvelis
    Gy. Török
    A. E. Sokolov
    V. A. Trunov
    V. V. Bakhmetyev
    A. A. Kotomin
    S. A. Dushenok
    A. S. Kozlov
    Semiconductors, 2012, 46 : 696 - 700
  • [2] Degradation and local distortions in electroluminescent ZnS:Cu,Cl phosphors
    Bridges, F.
    Medling, S.
    Balaban, B.
    Carter, S. A.
    11TH EUROPHYSICAL CONFERENCE ON DEFECTS IN INSULATING MATERIALS (EURODIM 2010), 2010, 15
  • [5] Luminescent mechanisms of ZnS:Cu:Cl and ZnS:Cu:Al phosphors
    Chen, YY
    Duh, JG
    Chiou, BS
    Peng, CG
    THIN SOLID FILMS, 2001, 392 (01) : 50 - 55
  • [6] Degradation and rejuvenation studies of AC electroluminescent ZnS:Cu,Cl phosphors
    Stanley, Jacob
    Jiang, Yu
    Bridges, Frank
    Carter, Sue A.
    Ruhlen, Laurel
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2010, 22 (05)
  • [7] Study of active surface centers in electroluminescent ZnS:Cu,Cl phosphors
    Sychov, MM
    Mjakin, SV
    Nakanishi, Y
    Korsakov, VG
    Vasiljeva, IV
    Bakhmetjev, V
    Solovjeva, O
    Komarov, EV
    APPLIED SURFACE SCIENCE, 2005, 244 (1-4) : 461 - 464
  • [8] Local degradation of electroluminescent emission centers in ZnS:Cu,Cl phosphors
    Medling, S.
    Bridges, F.
    Carter, S. A.
    JOURNAL OF LUMINESCENCE, 2013, 134 : 251 - 254
  • [9] ELECTRO-LUMINESCENCE OF ZNS, IN, CL AND ZNS, CU, IN, CL PHOSPHORS
    MAHESHWARI, RC
    PATHAK, KS
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 1982, 20 (11) : 855 - 857
  • [10] Effect of shock wave treatment on luminescence of ZnS:Cu,Cl phosphors
    Sychov, Maxim
    Bakhmetyev, Vadim
    Kotomin, Alexandr
    Dushenok, Sergey
    Kozlov, Alexey
    Tamamura, Hideo
    Nakanishi, Yoichiro
    Hara, Kazuhiko
    Kominami, Hiroko
    Mimura, Hidenori
    OPTICAL MATERIALS, 2015, 42 : 174 - 177