A microporous, moisture-stable, and amine-functionalized metal-organic framework for highly selective separation of CO2 from CH4

被引：72
|
作者：
Yuan, Bizhen [1 ]
Ma, Deyun [1 ,2 ]
Wang, Xi [1 ]
Li, Zhong [1 ]
Li, Yingwei [1 ]
Liu, Huimin [3 ]
He, Dehua [3 ]
机构：
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] Zhaoqing Univ, Coll Chem & Chem Engn, Zhaoqing 526061, Peoples R China
[3] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 08期
关键词：
CARBON-DIOXIDE; HYDROGEN STORAGE; GAS-ADSORPTION; ADSORBENTS; CAPACITY; SORPTION; METHANE; CO2/CH4; MIL-53; WATER;
D O I：
10.1039/c2cc16923a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new microporous amino-functionalized metal-organic framework has been synthesized by direct self-assembly, which exhibits high moisture-stability, acceptable capacity, and unprecedented high selectivity for CO2 over CH4, suggesting its potential application in gas separation processes like natural gas and biogas upgrading.
引用
收藏
页码：1135 / 1137
页数：3
相关论文
共 50 条
  • [1] An Amine-Functionalized MIL-53 Metal-Organic Framework with Large Separation Power for CO2 and CH4
    Couck, Sarah
    Denayer, Joeri F. M.
    Baron, Gino V.
    Remy, Tom
    Gascon, Jorge
    Kapteijn, Freek
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) : 6326 - +
  • [2] Amine-Functionalized MIL-53 Metal-Organic Framework in Polyimide Mixed Matrix Membranes for CO2/CH4 Separation
    Chen, Xiao Yuan
    Vinh-Thang, Hoang
    Rodrigue, Denis
    Kaliaguine, Serge
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (19) : 6895 - 6906
  • [3] Mixed matrix membranes incorporated with amine-functionalized titanium-based metal-organic framework for CO2/CH4 separation
    Guo, Xiangyu
    Huang, Hongliang
    Ban, Yujie
    Yang, Qingyuan
    Xiao, Yuanlong
    Li, Yanshuo
    Yang, Weishen
    Zhong, Chongli
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2015, 478 : 130 - 139
  • [4] A moisture stable metal-organic framework for highly efficient CO2/N2, CO2/CH4 and CO2/CO separation
    Li, Yong-Zhi
    Wang, Gang -Ding
    Lu, Shijian
    Xu, Fan
    Zhang, Han
    Sui, Yanwei
    Hou, Lei
    [J]. CHEMICAL ENGINEERING JOURNAL, 2024, 484
  • [5] A Stable Amine-Functionalized Microporous Metal-Organic Framework for Thermodynamically and Kinetically Selective Gas Separations
    Tian, Yuanyuan
    Mu, Bin
    Li, Bo
    Li, Xing
    Xu, Wei
    Lin, Yichao
    [J]. CHEMISTRYSELECT, 2019, 4 (13): : 3841 - 3847
  • [6] Amine-Functionalized Metal Organic Framework as a Highly Selective Adsorbent for CO2 over CO
    Wang, Xingrui
    Li, Huiquan
    Hou, Xin-Juan
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (37): : 19814 - 19821
  • [7] Efficient separation of CO2 from CH4 and N2 in an ultra-stable microporous metal-organic framework
    He, Chaohui
    Zhang, Peng
    Ma, Sai
    Zhang, Yujuan
    Hu, Tuoping
    [J]. DALTON TRANSACTIONS, 2023, 52 (23) : 7975 - 7981
  • [8] Development of Amine-Functionalized Metal-Organic Frameworks Hollow Fiber Mixed Matrix Membranes for CO2 and CH4 Separation: A Review
    Sunder, Naveen
    Fong, Yeong Yin
    Bustam, Mohamad Azmi
    Suhaimi, Nadia Hartini
    [J]. POLYMERS, 2022, 14 (07)
  • [9] A robust microporous ytterbium metal-organic framework with open metal sites for highly selective adsorption of CO2 over CH4
    Gao, Fengxian
    Li, Yue
    Ye, Yingjie
    Zhao, Longtao
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 86 : 137 - 139
  • [10] A Moisture-Stable 3D Microporous CoII-Metal-Organic Framework with Potential for Highly Selective CO2 Separation under Ambient Conditions
    Chand, Santanu
    Pal, Arun
    Das, Madhab C.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (22) : 5982 - 5986
12345