Adsorption Characteristics and Influencing Factors of Chlorimuron-Ethyl in Two Typical Chinese Soils

被引:7
|
作者
Ren, Wenjie [1 ,2 ]
Wang, Meie [3 ]
Zhou, Qixing [1 ,4 ]
机构
[1] Chinese Acad Sci, Inst Appl Ecol, Key Lab Terr Ecol Proc, Shenyang 110016, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Urban & Reg Ecol, Beijing 100085, Peoples R China
[4] Nankai Univ, Coll Environm Sci & Engn, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
SULFONYLUREA HERBICIDES; METSULFURON-METHYL; SORPTION/DESORPTION BEHAVIOR; ETHAMETSULFURON-METHYL; THIFENSULFURON-METHYL; BENSULFURON-METHYL; ORGANIC AMENDMENT; SORPTION; DESORPTION; MECHANISMS;
D O I
10.2136/sssaj2010.0228
中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
The adsorption of chlorimuron-ethyl in two typical northeastern Chinese soils before and aft er removal of organic matter and removal of organic matter plus iron/aluminum oxides was investigated using batch equilibrium methods, and the effect of pH on the adsorption was also evaluated. The adsorption kinetics were fitted well with the Elovich and pseudo-second-order kinetic models (R-2 = 0.973-0.985) and the adsorption isotherms conformed to the Linear, Freundlich, and Langmuir models (R-2 > 0.963). The mineral fraction appeared to dominate adsorption of chlorimuron-ethyl in brown earth (BE; Alfisols), while organic matter was the major component for the adsorption in black soil (BS; Mollisols). The adsorption of chlorimuron-ethyl in the original and treated soils all decreased with increasing pH. Moreover, the effect of pH on the adsorption of chlorimuron-ethyl in soil minerals was stronger than that in organic matter at acidic conditions.
引用
收藏
页码:1394 / 1401
页数:8
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