Effects of surface modification and surfactants on stability and thermophysical properties of TiO2/water nanofluids

被引:22
|
作者
Zhang, Hao [1 ,2 ]
Qing, Shan [1 ,2 ]
Gui, Qihao [1 ,2 ]
Zhang, Xiaohui [1 ,2 ]
Zhang, Aimin [2 ]
机构
[1] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Yunnan, Peoples R China
[2] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanofluids; Surfactants; Surface modification; Stability; Thermophysical properties; ENHANCED THERMAL-CONDUCTIVITY; SILANE COUPLING AGENT; HEAT-TRANSFER; VISCOSITY; TIO2; OXIDE; SUSPENSIONS; PARTICLES; TEMPERATURE; SIZE;
D O I
10.1016/j.molliq.2021.118098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2/water nanofluids are prepared by adding different surfactants and utilizing surface modification technique. The dispersion stability of TiO2 in water is evaluated, and better stability is found in Tetramethylammonium hydroxide (TMAH) added nanofluids and 3-aminpropyltriethoxysilane (APTS) treated nanofluids. Then the effects of nanoparticle concentration and temperature on thermophysical properties of the above two nanofluids are investigated. The viscosity of nanofluids increases with the increase of nanoparticle concentration, and decreases with temperature. The viscosity of APTS treated TiO2/water nanofluids is obvious higher than that of TMAH added TiO2/water nanofluids, because the grafting of APTS enhances the adhesion of nanoparticles to water. The thermal conductivity and effective thermal conductivity of nanofluids increases with the increase of temperature and nanoparticle concentration. And the changing trends and enhancement ratios of thermal conductivity for two nanofluids are similar. Finally, by applying properties enhancement ratio (PER), the thermal performance of TiO2/water nanofluids is evaluated. (C) 2021 Elsevier B.V. All rights reserved.
引用
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页数:13
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