Two Zn(II)-based coordination polymers as dual-responsive luminescent sensors for the detection of Cr2O72- ions, levofloxacin/sulfamethoxazole

被引:6
|
作者
Zhang, Xu-Peng [1 ]
Fu, Lianshe [2 ,3 ]
Cui, Guang-Hua [1 ]
机构
[1] North China Univ Sci & Technol, Coll Chem Engn, Hebei Key Lab Environm Photocatalyt & Electrocatal, 21 Bohai Rd, Tangshan 063210, Hebei, Peoples R China
[2] Univ Aveiro, Dept Phys, P-3810193 Aveiro, Portugal
[3] Univ Aveiro, CICECO Aveiro Inst Mat, P-3810193 Aveiro, Portugal
关键词
Coordination polymers; Cr(2)O(7)(2-)Fluorescence; Levofloxacin; Sulfamethoxazole; Zinc(II);
D O I
10.1016/j.inoche.2022.109761
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new ternary coordination polymers (CPs), namely, [Zn(NBTA)(HL)](n) (1) and {[Zn(4-NPA)(L)]center dot H2O}n (2) (H(3)NBTA = 5-nitro-1,2,3-benzenetricarboxylic acid, 4-H(2)NPA = 4-nitrophthalic acid, L = 1,4-bis(benzimidazol-2-yl)butane were hydrothermally synthesized and characterized. 1 possesses a 1D straight chain, which is further extended into a 2D supramolecular network through pi-pi stacking interactions. 2 exhibits the 2D hcb layer. The two CPs present highly thermal and chemical stabilities in the pH range from 3 to 12. 1 and 2 can selectively detect Cr2O72--ions/levofloxacin, and Cr(2)O(7)(2-)ions/sulfamethoxazole, respectively, with recyclability and low detection limits.
引用
收藏
页数:8
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