Alkali metal salts of acrylamide C(3)H(4)NOM (M=Li, Na, and K): Synthesis and vibrational spectra

被引：3
|
作者：
Chekulaeva, LA
Garbuzova, IA
Gavrilenko, VV
Danilevskaya, LB
Kotelnikov, VA
机构：
来源：
RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 09期
关键词：
acrylamide; alkali metals; salts; anionic polymerization; IR spectra; Raman spectra;
D O I：
10.1007/BF01430740
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkali metal salts of acrylamide C(3)H(4)NOM (M = Li, Na, and K) were synthesized for the first time by metallation of acrylamide with alkali metals, their alkyl derivatives, or hydrides. The structures of the compounds synthesized were studied by Raman and IR spectroscopy. Based on the results obtained, an ionic structure was proposed for the salts. The salts were tested as initiators of the anionic polymerization of acrylamide. The catalytic activity of C(3)H(4)NOM in the polymerization of acrylamide is not lower than that of the well known catalyst, KOBu(t).
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页码：2199 / 2202
页数：4
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