Structure of a self-assembled network made of polymeric worm-like micelles

被引：6
|
作者：
Moussa, Wissam [1 ]
Colombani, Olivier [1 ]
Benyahia, Lazhar [1 ]
Nicolai, Taco [1 ]
Chassenieux, Christophe [1 ]
机构：
[1] Univ Maine, PRES LUNAM, IMMM UMR CNRS Dept Polymeres Colloides Interfaces, Ave O Messiaen, F-72085 Le Mans 9, France
来源：
POLYMER BULLETIN | 2016年 / 73卷 / 10期
关键词：
ALKANEDIYL-ALPHA; OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS; AQUEOUS-SOLUTIONS; LINEAR VISCOELASTICITY; DIMERIC SURFACTANTS; FORMING MONOMERS; PHOTOPOLYMERIZATION; TRANSITION; COPOLYMERS; STYRENE; SYSTEMS;
D O I：
10.1007/s00289-016-1615-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The self-assembly of polymeric worm-like micelles in water was studied by rheology, light scattering and small angle neutron scattering. The polymer was synthesized by randomly grafting pendant quaternized alkylamine moieties to a polystyrene chain. The rheological properties of the gels evolve greatly over time: the elastic modulus G' increases up to a maximum and then decreases. It is possible to obtain a kinetic master curve of evolution of the G' at different temperatures. Structural measurements show the presence of heterogeneities that disappear slowly in time or when the samples are heated.
引用
收藏
页码：2689 / 2705
页数：17
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