Stereodynamics in dissociative adsorption of NO on Si(111)

被引：16

作者：

Hashinokuchi, M. ^{[1
]}

Okada, M. ^{[1
,2
]}

Ito, H. ^{[1
]}

Kasai, T. ^{[1
]}

Moritani, K. ^{[3
]}

Teraoka, Y. ^{[3
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 5600043, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Saitama 3320012, Japan

[3] Japan Atom Energy Agcy, Synchrotron Radiat Res Ctr, Sayo, Hyogo 6795148, Japan

来源：

PHYSICAL REVIEW LETTERS | 2008年 / 100卷 / 25期

基金：

日本学术振兴会;

关键词：

D O I：

10.1103/PhysRevLett.100.256104

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We report results of our study on the surface-temperature dependence of the steric effect in the dissociative adsorption of NO on Si(111)-(7 x 7). Data presented here show that, at an incident energy of 58 meV, the reactive sticking probability for the N-end collision is larger than that for the O-end collision. Furthermore, this steric preference is quite sensitive to the surface temperature and the surface coverage. This study shows that the transient surface trapping into a shallow precursor well plays a key role in the stereodynamics of the dissociative adsorption at the low energy region.

引用

页数：4

共 50 条

[1] DISSOCIATIVE ADSORPTION OF NH3 ON CLEAVED SI(111)
CHERIF, SM
LACHARME, JP
SEBENNE, CA
[J]. SURFACE SCIENCE, 1992, 274 (02) : 257 - 262
[2] METASTABLE MOLECULAR PRECURSOR FOR THE DISSOCIATIVE ADSORPTION OF OXYGEN ON SI(111)
HOFER, U
MORGEN, P
WURTH, W
UMBACH, E
[J]. PHYSICAL REVIEW LETTERS, 1985, 55 (27) : 2979 - 2982
[3] Dissociative adsorption of nitric oxide on Si(111)-(7 × 7) surface
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
不详
不详
[J]. Jpn. J. Appl. Phys., 1600, 3 PART 1 (1672-1676):
[4] Dissociative adsorption of pyrrole on Si(111)-(7x7)
Yuan, ZL
Chen, XF
Wang, ZH
Yong, KS
Cao, Y
Xu, GQ
[J]. JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (19): : 10389 - 10395
[5] The dissociative adsorption of unsaturated alcohols on Si(111)-7x7
Tang, Hai Hua
Dai, Yu Jing
Shao, Yan Xia
Ning, Yue Sheng
Huang, Jing Yan
Lai, Yee Hing
Peng, Bo
Huang, Wei
Xu, Guo Qin
[J]. SURFACE SCIENCE, 2008, 602 (15) : 2647 - 2657
[6] Dissociative adsorption of nitric oxide on Si(111)-(7x7) surface
Hashinokuchi, Michihiro
Ito, Hironori
Teraoka, Yuden
Moritani, Kousuke
Okada, Michio
Kasai, Toshio
[J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 2008, 47 (03) : 1672 - 1676
[7] Dissociative adsorption and thermal evolution of carbon tetrachloride on Si(111)7 x 7
Venugopal, V.
Ebrahimi, M.
He, Z. H.
Leung, K. T.
[J]. SURFACE SCIENCE, 2008, 602 (18) : 3000 - 3005
[8] Stereodynamics in O2 adsorption on Si(100)
Kurahashi, Mitsunori
Yamauchi, Yasushi
[J]. Journal of the Vacuum Society of Japan, 2015, 58 (01) : 13 - 19
[9] Bromine dissociative adsorption and etching on Pt(111).
Harrison, I
Xu, HW
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U557 - U557
[10] Molecular adsorption and dissociative reaction of oxygen on the Si(111)7X7 surface
Hoshino, T
Nishioka, Y
[J]. PHYSICAL REVIEW B, 2000, 61 (07): : 4705 - 4713

← 1 2 3 4 5 →