Thermodynamics and kinetic studies of insertion reaction between CCl and NH3

被引：0

作者：

Si, Weijiang ^{[1
]}

Zhuo, Shuping ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Chem Engn, Zibo 255091, Peoples R China

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2008年 / 47卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on the quantum theoretical study of the insertion reaction of CCl with NH3, the statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the thermodynamic functions, the equilibrium constants, A factors and the rate constants in the temperature range 200-2000K. Results show that the reaction is thermodynamically dominant at low temperatures and kinetically favoured at higher temperatures.

引用

页码：556 / 559

页数：4

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