Regio- and stereoselective synthesis of 1,4-dienes

被引：13

作者：

Oishi, Shigeki ^{[1
]}

Hatano, Keisuke ^{[1
]}

Tsubouchi, Akira ^{[1
]}

Takeda, Takeshi ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Grad Sch Engn, Koganei, Tokyo 1848588, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 42期

关键词：

TERMINATED PRINS REACTION; STEREOSPECIFIC SYNTHESIS; SUBSTITUTED 1,4-DIENES; HYDROVINYLATION; ALKYLATION; ALCOHOLS; DIENES; ALKYNE; ESTERS;

D O I：

10.1039/c1cc14765j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Titanocene(II)-promoted cross-coupling between (Z)-alkenyl methyl sulfones and terminal allenes produced 1,4-dienes regioselectively via the formation of 2-alkylidenetitanacyclopentanes. Preferential formation of E,Z-dienes was observed in the reaction using aryl-, amino-, and phosphinylallenes.

引用

页码：11639 / 11640

页数：2

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