Eutectic ionic liquid mixtures and their effect on CO2 solubility and conductivity

被引:15
|
作者
Ivanova, Anna S. [1 ]
Brinzer, Thomas [2 ]
Roth, Elliot A. [4 ]
Kusuma, Victor A. [4 ]
Watkins, John D. [4 ]
Zhou, Xu [3 ,4 ]
Luebke, David [4 ]
Hopkinson, David [4 ]
Washburn, Newell R. [1 ]
Garrett-Roe, Sean [2 ]
Nulwala, Hunaid B. [1 ,4 ]
机构
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
[2] Univ Pittsburgh, Dept Chem, Chevron Sci Ctr, Pittsburgh, PA 15260 USA
[3] Liquid Ion Solut LLC, Pittsburgh, PA 15205 USA
[4] Natl Energy Technol Lab, Pittsburgh, PA 15236 USA
关键词
THERMOPHYSICAL PROPERTIES; BINARY-MIXTURES; CARBON-DIOXIDE; 1-HEXYL-3-METHYLIMIDAZOLIUM; BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; ABSORPTION; TRANSITION; CAPTURE;
D O I
10.1039/c5ra06561e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple binary system of compounds resembling short-chain versions of popular ionic liquids has been shown to have surprisingly complex properties. Combining methylated versions of pyridinium and pyrrolidinium bis[(trifluoromethyl) sulfonyl] imide gave desirable properties such as low viscosity and high conductivity solubility per unit volume. The binary combinations studied in this study showed that these materials were stable liquids at 50 degrees C and had a threefold improvement in conductivity over [C(6)C(1)im] [Tf2N]. Despite the high densities of these materials, 2D-IR studies indicate increased ion mobility, likely due to the lack of hindering alkyl chains.
引用
收藏
页码:51407 / 51412
页数:6
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