Platinum-Rare Earth Alloy Electrocatalysts for the Oxygen Reduction Reaction: A Brief Overview

被引:19
|
作者
Campos-Roldan, Carlos A. [1 ]
Jones, Deborah J. [1 ]
Roziere, Jacques [1 ]
Cavaliere, Sara [1 ,2 ]
机构
[1] Univ Montpellier, CNRS, ENSCM, ICGM, F-34095 Montpellier 5, France
[2] Inst Univ France IUF, F-75231 Paris 5, France
基金
欧洲研究理事会; 欧盟地平线“2020”;
关键词
Electrocatalysis; Fuel Cells; Oxygen Reduction Reaction; Platinum alloys; Rare Earth Metals; ENHANCED ACTIVITY; FUEL-CELLS; PT-LA; STABILITY; NANOPARTICLES; CATALYSTS; ELECTROREDUCTION; LANTHANIDE; NANOMATERIALS; FABRICATION;
D O I
10.1002/cctc.202200334
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of highly active and long-term stable electrocatalysts for the cathode of proton-exchange membrane fuel cells (PEMFC) is a paramount requirement for high performance and durable PEMFC stacks. In this regard, alloying Pt with rare earth metals (REM) has emerged as a promising approach. This short review summarizes and discusses the most relevant advances on Pt-REM alloy electrocatalysts, from bulk polycrystalline surfaces to carbon supported nanostructures, for the oxygen reduction reaction (ORR), and their implementation in PEMFCs, and is a starting point to establish the challenges in synthesis and design and properties goals for novel Pt-REM alloys.
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页数:11
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